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Influence of mineral transformation on emission of particulate matters during coal combustion

LIU Xiaowei, XU Minghou, YU Dunxi, GAO Xiangpeng, CAO Qian, HAO Wei

《能源前沿(英文)》 2007年 第1卷 第2期   页码 213-217 doi: 10.1007/s00000-007-0028-4

摘要: Combustion of pulverized coal was studied in a drop tube furnace to understand coal mineral properties with the emission of particulate matters (PM). Experimental conditions were selected as follows: coal particle size was smaller than 63 μm; reaction temperature was 1 100vH, 1 250vH and 1 400vH respectively; oxygen content was 20% and 50% respectively. PM was collected with a 13-stagelow pressure impactor (LPI) having an aerodynamic cut-off diameter ranging from 10.0 μm to 0.03 μm for a size-segregated collection. Such properties as concentration, particle size distribution and elemental composition of PM were investigated. The experimental results indicate that the emitted PM has a bimodal distribution having two peaks around 4.0 μm and 0.1 μm. Increasing temperature leads to the formation of more PM; varied oxygen content leads to much change of emitted PM. PM was also subjected to XRF analysis to quantify the elemental composition. The results show that PM of 0.1 μm is rich in sulfates. Meanwhile, SiO and AlO are prevalent in PM of 4.0 μm, which means that the last peak around 4.0 μm is mainly aluminosilicate salts.

关键词: prevalent     Combustion     cut-off diameter     temperature     particle    

Atmospheric heterogeneous reaction of chlorobenzene on mineral -FeO particulates: a chamber experiment

《环境科学与工程前沿(英文)》 2023年 第17卷 第11期 doi: 10.1007/s11783-023-1734-9

摘要:

● Photochemical conversion of chlorobenzene (CB) on α-Fe2O3 was evaluated.

关键词: Photochemical conversion     Chlorobenzene     α-Fe2O3     PCDD/Fs     Mineral particulate    

Cylindrical particulate internal flows: A review

Lizhong HUANG, Xiang GAO, Jianzhong LIN

《机械工程前沿(英文)》 2012年 第7卷 第4期   页码 385-393 doi: 10.1007/s11465-012-0354-z

摘要:

The study of cylindrical particulate internal flows has wide industrial applicability hence received much attention. This article reviews the cylindrical particulate internal flows over the past twenty years. The research is related to the cylindrical particulate flows in the straight channel, curved channel and rotational channel. Finally, several open research issues have been identified.

关键词: cylindrical particulate flow     internal flow    

A method for quantifying bias in modeled concentrations and source impacts for secondary particulate

Cesunica E. Ivey, Heather A. Holmes, Yongtao Hu, James A. Mulholland, Armistead G. Russell

《环境科学与工程前沿(英文)》 2016年 第10卷 第5期 doi: 10.1007/s11783-016-0866-6

摘要: A method for quantifying source impacts for secondary PM species is derived. The method provides estimates of bias in modeled concentrations. Adjusted concentrations match corresponding observations at monitored locations. Sources impacts on secondary species are estimated over the US for 20 sources. Community Multi-Scale Air Quality (CMAQ) estimates of sulfates, nitrates, ammonium, and organic carbon are highly influenced by uncertainties in modeled secondary formation processes, such as chemical mechanisms, volatilization, and condensation rates. These compounds constitute the majority of PM mass, and reducing bias in estimated concentrations has benefits for policy measures and epidemiological studies. In this work, a method for adjusting source impacts on secondary species is developed that provides estimates of source contributions and reduces bias in modeled concentrations compared to observations. The bias correction adjusts concentrations and source impacts based on the difference between modeled concentrations and observations while taking into account uncertainties at the location of interest; and it is applied both spatially and temporally. We apply the method over the US for 2006. The mean bias for initial CMAQ concentrations compared to observations is −0.28 (OC), 0.11 (NO ), 0.05 (NH ), and −0.08 (SO ). The normalized mean bias in modeled concentrations compared to observations was effectively zero for OC, NO , NH , and SO after applying the secondary bias correction. 10-fold cross-validation was conducted to determine the performance of the spatial application of the bias correction. Cross-validation performance was favorable; correlation coefficients were greater than 0.69 for all species when comparing observations and concentrations based on kriged correction factors. The methods presented here address model uncertainties by improving simulated concentrations and source impacts of secondary particulate matter through data assimilation. Secondary-adjusted concentrations and source impacts from 20 emissions sources are generated for 2006 over continental US.

关键词: Particulate matter     Source apportionment     Secondary particulate matter     Chemical transport modeling     Receptor modeling    

Vanadium and molybdenum concentrations in particulate from Palermo (Italy): analytical methods using

Diana AMORELLO,Santino ORECCHIO

《环境科学与工程前沿(英文)》 2015年 第9卷 第4期   页码 605-614 doi: 10.1007/s11783-014-0703-8

摘要: The main purpose of this work was to develop a reliable method for the determination of vanadium (V) and molybdenum (Mo) in atmosphere particles or aerosols because they can not be readily measured using conventional techniques. For this research, 30 particulate samples were collected from five different stations located at Palermo, Italy. We used the catalytic adsorptive stripping voltammetry and differential pulsed voltammetry to measure V and Mo in atmospheric particulate, respectively. The represented method includes advantages of high sensitivity, high selectivity, simplicity, reproducibility, speed and low costs. The quantification limits for V and Mo are, respectively, 0.57 and 0.80 ng·m . The precision, expressed as relative standard deviation (RSD %), was about 2% for both metals. The mean recoveries of added V and Mo were about 99.5% and ranged from 97% to 101%. Vanadium concentrations in particulate samples collected in Palermo area ranged from 0.57 to 7.7 ng·m , while Mo concentrations were in the range 0.8–51 ng·m . In many cases the concentrations of two elements in the particulate samples fall below the detection limits. The mean concentrations for V and Mo in particulate samples, collected in Palermo area, were respectively 3.1 and 5.9 ng·m .

关键词: vanadium     molybdenum     particulate     voltammetry     Palermo    

Effects of exercise therapy on bone mineral density in early postmenopausal women: a controlled trial

Shilin DENG MD ,

《医学前沿(英文)》 2009年 第3卷 第3期   页码 323-329 doi: 10.1007/s11684-009-0061-2

摘要: The purpose of this article is to determine the effect of a well-designed combined aerobic, resistance, and extension exercise program on bone mineral density (BMD) in postmenopausal women. The population comprised 45 postmenopausal women, who exercised over 12months (exercise group), and 36 women who served as a non-training control group. BMD of the hip, and lumbar spine was measured at the baseline and 12th month. Repeated measurement analysis of variance and nonparametric test were utilized to compare differences between the exercise group and controls. Thirty-six out of 45 persons in the exercise group and 36 controls completed the study. Average compliance was 82.2% for the whole exercise group at the 12th month. All the subjects had decreased BMD, but the rate of bone loss was lower in the exercise group than in the control group at the L4 and hip. Although the exercise program in this study may probably reduce the rate of bone loss in weight-bearing skeletal sites, we do not suggest the exercise by itself be viewed as prevention or treatment for osteoporosis. Further, the exact dose-response relationship of exercise and bone mass in early postmenopause is not clear.

关键词: early postmenopausal women     bone mineral density     exercise     effects    

矿物浮选吸附平衡模型构建与应用:精准解析矿物 表面离子 / 药剂特征吸附

高雅,付心壮,韩海生,王丽,岳彤,孙伟

《中国工程科学》 2023年 第25卷 第6期   页码 248-258 doi: 10.15302/J-SSCAE-2023.07.020

摘要:

矿物浮选吸附平衡模型是准确描述矿物浮选过程中所涉及的矿物表面离子 / 药剂吸附平衡的数学模型,首次实现了矿物表面位点与浮选药剂吸附作用亲和性的量化解析。传统浮选理论对矿物表面作用位点缺乏科学描述,难以阐明浮选药剂的吸附作用能力及平衡状态,新浮选药剂体系开发多以“试错法”“复配法”等经验性方法为主。药剂选择性吸附作为浮选作业的核心机制,若不能准确预测其在各矿物表面的吸附行为,将严重限制浮选工艺智能化控制的发展。本文详细论述了矿物浮选吸附平衡模型的构建原理,以赤铁矿 ‒ 石英和一水硬铝石 ‒ 高岭石两个浮选体系为例,通过对少量实验数据的拟合计算,解析出矿物表面活性位点密度Ns、加 / 去质子反应常数Kt1/Kt2、药剂吸附常数Kf等矿物浮选特征常数。将解析的矿物浮选特征常数代入到平衡模型中,预测出各条件下矿物表面电性、离子及浮选药剂的吸附量,通过零电点、实验及测试等方法验证了可靠性,形成了矿物浮选过程预测系统的内核算法。该算法对各条件下每种矿物药剂吸附的初步准确预测,可在一定程度上反映其可浮性趋势,有助于缩短浮选工艺开发周期,对矿物表面药剂吸附机理研究、浮选药剂分子设计、浮选工艺流程优化及智能控制等具有重要意义。

关键词: 矿物加工;浮选机理;矿物浮选吸附平衡模型;可浮性预测;矿物浮选特征常数    

Recent advances of hydrogen production through particulate semiconductor photocatalytic overall water

《能源前沿(英文)》 2022年 第16卷 第1期   页码 49-63 doi: 10.1007/s11708-022-0817-9

摘要: Solar energy-driven photocatalytic water splitting has been investigated for decades to produce clean and renewable green hydrogen. In this paper, the cutting-edge research within the overall water splitting system is summarized from the one-step photocatalytic overall water splitting (POWS) system to the two-step system and the cocatalysts research in this field. In addition, the photocatalytic reaction engineering study is also reviewed which is crucial for future scale-up. This mini-review provides a picture of survey of recent progress of relevant overall water splitting system, with particular attention paid to material system and mechanistic breakthroughs, and highlights the challenge and opportunity of the current system.

关键词: photocatalysis     overall water splitting     hydrogen    

Relationship between the development of energy and mineral resources and ecological conservation redline

Dawei ZHANG

《工程管理前沿(英文)》 2019年 第6卷 第4期   页码 557-563 doi: 10.1007/s42524-019-0077-5

摘要: From a philosophical point of view, this study discusses the dialectical relationship between the development of energy and mineral resources and the ecological conservation redline. We propose that the ecological conservation redline and the development of energy and mineral resources should be guided by ecological civilization construction, that is, the energy and mineral resources should be rationally developed under the condition that the ecological environment is protected. This study analyzes the influence of the development of energy and mineral resources on the ecological environment. The handling of mining rights within the ecological conservation redline based on the law and the reduction of the influence of the development of energy mineral resources on the ecological environment by science and technology are presented. The environmental assessment system and technical standards for energy and mineral development are suggested to implement policies and measures for the disposal of mining rights within the redline and facilitate technological innovations of ecological conservation for energy and mineral development. Hence, a coordinated development between the ecological conservation redline and the development of energy and mineral resources can be promoted.

关键词: ecological conservation redline     development of energy and mineral resources     coordinated development    

A state-of-the-art review on interfacial behavior between asphalt binder and mineral aggregate

Meng GUO, Yiqiu TAN, Linbing WANG, Yue HOU

《结构与土木工程前沿(英文)》 2018年 第12卷 第2期   页码 248-259 doi: 10.1007/s11709-017-0422-x

摘要: The interface between asphalt binder and mineral aggregate directly affects the service life of pavement because the defects and stress concentration occur more easily there. The interaction between asphalt binder and mineral aggregate is the main cause of forming the interface. This paper presents an extensive review on the test technologies and analysis methods of interfacial interaction, including molecular dynamics simulation, phase field approach, absorption tests, rheological methods and macro mechanical tests. All of the studies conducted on this topic clearly indicated that the interfacial interaction between asphalt binder and mineral aggregate is a physical-chemical process, and can be qualitatively characterized by microscopical technique (such as SEM and AFM), and also can be quantitatively evaluated by rheological methods and interfacial mechanical tests. Molecular dynamics simulation and phase field approach were also demonstrated to be effective methods to study the interfacial behavior and its mechanism.

关键词: Asphalt binder     Mineral aggregate     Interfacial behavior     Multiscale    

Seasonal variations in leaf capturing of particulate matter, surface wettability and micromorphology

Huixia WANG, Hui SHI, Yangyang LI, Ya YU, Jun ZHANG

《环境科学与工程前沿(英文)》 2013年 第7卷 第4期   页码 579-588 doi: 10.1007/s11783-013-0524-1

摘要: The seasonal changes in leaf particulate matter (PM) accumulation, surface wettability and micromorphology in urban tree species, including ( . ), ( . ) and ( . ), were studied during a single growing season. The three species showed distinct seasonal trends in PM accumulation, increasing from spring to autumn (or winter) even during the rainy season, but at different rates. During the study, the leaf PM retention amount of , a species with ridged leaf surfaces, was significantly higher than that of and , species with waxy leaf surfaces. The contact angles of water droplets on leaves decreased with leaf age except on the abaxial surface of , which remained non-wettable or highly non-wettable throughout the growing season; the decrease in the contact angle on adaxial surface of was greater when compared with and . A significant and negative relationship existed between leaf PM retention amounts and contact angles on adaxial surface of leaves of all three species. The increase in wettability, probably caused when epicuticular wax was destroyed by mechanical and chemical abrasion, seemed to be the main factor leading to seasonal variations in leaf PM accumulation.

关键词: contact angle     particulate matter     retention amount    

Pollution characteristics of particulate matters emitted from outdoor barbecue cooking in urban Jinan

Yifei Song, Lei Sun, Xinfeng Wang, Yating Zhang, Hui Wang, Rui Li, Likun Xue, Jianmin Chen, Wenxing Wang

《环境科学与工程前沿(英文)》 2018年 第12卷 第2期 doi: 10.1007/s11783-018-1024-0

摘要: To understand the pollution characteristics of particulate matter emitted from outdoor barbecue cooking in eastern China, measurements of the PM mass concentration, the number concentration of particles with a diameter of 0.01 to 1.0 m, and the particle size distribution from 0.3 to 25 m were carried out at seven barbecue restaurants in urban Jinan. The average PM mass concentration and sub-micron particle number concentrations at a distance of 1 m from the grills were 250 to 1083 g/m and 0.90 × 10 to 2.23 × 10 cm , respectively, which were much higher than those in the ambient air of the urban area. Compared to the ambient atmosphere, barbecue cooking emitted very high levels of particles with a larger increase in the concentrations of super-micron particles than that of sub-micron particles. The super-micron particle number concentrations at the barbecue restaurants were 10 to 100 times higher than those observed in the ambient urban atmosphere. The barbecue smoke had a significant effect on the particle concentrations in the surrounding region. Both mass and number concentrations of particles exhibited maximum values immediately near the barbecue grills and often reached a peak at a distance of 10 to 15 m. The removal efficiency of a range hood for the cooking particles was tested in an indoor kitchen. The range hood effectively cleaned the particulate matter pollution caused by cooking with a removal efficiency larger than 80%. Therefore, the use of a range hood is recommended for outdoor barbecue restaurants coupled with a smoke purifier to clean the emitted high concentrations of particles.To understand the pollution characteristics of particulate matter emitted from outdoor barbecue cooking in eastern China, measurements of the PM mass concentration, the number concentration of particles with a diameter of 0.01 to 1.0 m, and the particle size distribution from 0.3 to 25 m were carried out at seven barbecue restaurants in urban Jinan. The average PM mass concentration and sub-micron particle number concentrations at a distance of 1 m from the grills were 250 to 1083 g/m and 0.90 × 10 to 2.23 × 10 cm , respectively, which were much higher than those in the ambient air of the urban area. Compared to the ambient atmosphere, barbecue cooking emitted very high levels of particles with a larger increase in the concentrations of super-micron particles than that of sub-micron particles. The super-micron particle number concentrations at the barbecue restaurants were 10 to 100 times higher than those observed in the ambient urban atmosphere. The barbecue smoke had a significant effect on the particle concentrations in the surrounding region. Both mass and number concentrations of particles exhibited maximum values immediately near the barbecue grills and often reached a peak at a distance of 10 to 15 m. The removal efficiency of a range hood for the cooking particles was tested in an indoor kitchen. The range hood effectively cleaned the particulate matter pollution caused by cooking with a removal efficiency larger than 80%. Therefore, the use of a range hood is recommended for outdoor barbecue restaurants coupled with a smoke purifier to clean the emitted high concentrations of particles.

关键词: Barbecue smoke     Particulate matters     Pollution characteristics     Emissions     Removal    

Effect of mineral additives and permeability reducing admixtures having different action mechanisms on

《结构与土木工程前沿(英文)》 2021年 第15卷 第5期   页码 1277-1291 doi: 10.1007/s11709-021-1752-2

摘要: In this paper, the effect of usage of the permeability reducing admixture (PRA) having different action mechanisms on hardened state properties of cementitious systems containing mineral additives is examined. For this aim, three commercial PRAs were used during investigation. The effective parameters in the first and third PRAs were air-entraining and high-rate air-entraining, respectively. The second one contained the insoluble calcium carbonate residue and had a small amount of the air-entraining property. Mortar mixes with binary and ternary cementitious systems were prepared by partially replacing cement with fly ash and metakaolin. The hardened state properties of mortar mixtures such as compressive strength, ultrasonic pulse velocity, water absorption, drying shrinkage and freeze–thaw resistance were investigated. The ternary cement-based mixture having both fly ash and metakaolin was selected as the most successful mineral-additive bearing mix in regard to hardened state properties. In this sense, PRA-B, with both insoluble residues and a small amount of air-entraining properties, showed the best performance among the mixtures containing PRA. The combined use of mineral additive and PRA had a more positive effect on the properties of the mixes.

关键词: cementitious system     mineral additive     permeability reducing admixture     mechanical properties     durability performance    

Data sharing mechanism of various mineral resources based on blockchain

Yili REN, Jia LIANG, Jian SU, Gang CAO, He LIU

《工程管理前沿(英文)》 2020年 第7卷 第4期   页码 592-604 doi: 10.1007/s42524-020-0132-2

摘要: Basins with various mineral resources coexisting and enriching often occupy an important strategic position. The exploration of various mineral resources is repetitive at present due to unshared data and imperfect management mechanism. This situation greatly increases the cost of energy exploitation in the country. Traditional data-sharing mode has several disadvantages, such as high cost, difficulty in confirming the right of data, and lack of incentive mechanism, which make achieving real data sharing difficult. In this paper, we propose a data-sharing mechanism based on blockchain and provide implementation suggestions and technical key points. Compared with traditional data-sharing methods, the proposed data-sharing mechanism can realize data sharing, ensure data quality, and protect intellectual property. Moreover, key points in the construction are stated in the case study section to verify the feasibility of the data-sharing system based on blockchain proposed in this paper.

关键词: data sharing     blockchain     various mineral resources     collaborative exploration     big data    

Determination of polyfluoroalkyl compounds in water and suspended particulate matter in the river Elbe

Lutz AHRENS, Merle PLASSMANN, Zhiyong XIE, Ralf EBINGHAUS

《环境科学与工程前沿(英文)》 2009年 第3卷 第2期   页码 152-170 doi: 10.1007/s11783-009-0021-8

摘要: The distribution of polyfluoroalkyl compounds (PFCs) in the dissolved and particulate phase and their discharge from the river Elbe into the North Sea were studied. The PFCs quantified included C -C perfluorinated sulfonates (PFSAs), 6∶2 fluorotelomer sulfonate (6∶2 FTS), C and C perfluorinated sulfinates (PFSiAs), C -C perfluorinated carboxylic acids (PFCAs), perfluoro-3,7-dimethyl-octanoic acid (3,7m -PFOA), perfluorooctane sulfonamide (FOSA), and n-ethyl perfluroctane sulfonamidoethanol (EtFOSE). PFCs were mostly distributed in the dissolved phase, where perfluorooctanoic acid (PFOA) dominated with 2.9-12.5 ng/L. In the suspended particulate matter FOSA and perfluorooctane sulfonate (PFOS) showed the highest concentrations (4.0 ng/L and 2.3 ng/L, respectively). The total flux of ∑PFCs from the river Elbe was estimated to be 802 kg/year for the dissolved phase and 152 kg/year for the particulate phase. This indicates that the river Elbe acts as a source of PFCs into the North Sea. However, the concentrations of perfluorobutane sulfonate (PFBS) and perfluorobutanoic acid (PFBA) in the North Sea were higher than that in the river Elbe, thus an alternative source must exist for these compounds.

关键词: polyfluoroalkyl compounds (PFCs)     perfluorooctane sulfonate (PFOS)     perfluorooctanoic acid (PFOA)     surface water     water-particulate partitioning    

标题 作者 时间 类型 操作

Influence of mineral transformation on emission of particulate matters during coal combustion

LIU Xiaowei, XU Minghou, YU Dunxi, GAO Xiangpeng, CAO Qian, HAO Wei

期刊论文

Atmospheric heterogeneous reaction of chlorobenzene on mineral -FeO particulates: a chamber experiment

期刊论文

Cylindrical particulate internal flows: A review

Lizhong HUANG, Xiang GAO, Jianzhong LIN

期刊论文

A method for quantifying bias in modeled concentrations and source impacts for secondary particulate

Cesunica E. Ivey, Heather A. Holmes, Yongtao Hu, James A. Mulholland, Armistead G. Russell

期刊论文

Vanadium and molybdenum concentrations in particulate from Palermo (Italy): analytical methods using

Diana AMORELLO,Santino ORECCHIO

期刊论文

Effects of exercise therapy on bone mineral density in early postmenopausal women: a controlled trial

Shilin DENG MD ,

期刊论文

矿物浮选吸附平衡模型构建与应用:精准解析矿物 表面离子 / 药剂特征吸附

高雅,付心壮,韩海生,王丽,岳彤,孙伟

期刊论文

Recent advances of hydrogen production through particulate semiconductor photocatalytic overall water

期刊论文

Relationship between the development of energy and mineral resources and ecological conservation redline

Dawei ZHANG

期刊论文

A state-of-the-art review on interfacial behavior between asphalt binder and mineral aggregate

Meng GUO, Yiqiu TAN, Linbing WANG, Yue HOU

期刊论文

Seasonal variations in leaf capturing of particulate matter, surface wettability and micromorphology

Huixia WANG, Hui SHI, Yangyang LI, Ya YU, Jun ZHANG

期刊论文

Pollution characteristics of particulate matters emitted from outdoor barbecue cooking in urban Jinan

Yifei Song, Lei Sun, Xinfeng Wang, Yating Zhang, Hui Wang, Rui Li, Likun Xue, Jianmin Chen, Wenxing Wang

期刊论文

Effect of mineral additives and permeability reducing admixtures having different action mechanisms on

期刊论文

Data sharing mechanism of various mineral resources based on blockchain

Yili REN, Jia LIANG, Jian SU, Gang CAO, He LIU

期刊论文

Determination of polyfluoroalkyl compounds in water and suspended particulate matter in the river Elbe

Lutz AHRENS, Merle PLASSMANN, Zhiyong XIE, Ralf EBINGHAUS

期刊论文